By A. R. Katritzky, A. J. Boulton

ISBN-10: 0120206161

ISBN-13: 9780120206162

During this quantity 3 of the chapters take care of particular ring platforms: 1,2,3-triazoles (T. L. Gilchrist and G. E. Gymer), dibenzothiophenes (J. Ashby and С. С Cook), and the 7-azabicyclo[2.2.1]heptadienes, and their lowered, and benzo-fused, derivatives (L. J. Kricka and J. M. Vernon). 3 extra chapters conceal specific points of heterocyclic compounds as a rule: cationic cycloaddition reactions (С. К. Bradsher), homolytic fragrant substitution (F. Minisci and nil. Porta), and base-catalyzed hydrogen alternate (of ring protons) (J. A. Elvidge, J. R. Jones, zero. O'Brien, E. A. Evans, and H. C. Sheppard).

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Rossi, J . Chem. ,Perkin 86, Trans. 1 , 6 1 9 , 769 (1972); Y. K. Kim and M. E. Munk, J . Amer. Chem. SOC. 2213 (1964); M. Regitz and G. Himbert, Ann 734, 70 (1970). Bianchetti, P. Dalla Croce, and D. Pocar, Gazz. Chim. Ital. 94, 340 (1964). 92 P. N. Neuman, J . Heterocycl. Chem. 8, 51 (1971). 93 P. Ferruti, D. Pocar, and G. Bianchetti, Gazz. Chim. Ital. 97, 109 (1967). 94 D. Pocar, S. Maiorana, and P. Dalla Croce, Gazz. Chim. Ital. 98, 949 (1968). g5 G. Bianchetti, D. Pocar, P. Dalla Croce, and A.

Naz. , Mat. Nut. 41, 204 (1966) ; Chem. Abstr. 67, 54080 (1967). 2 3 R. E. Harmon, R . A. Earl, and S . K. Gupta, Chem. Commun. 296 (1971). 24 J. C. Sheehan and C. A. Robinson, J . Amer. Chem. SOC. 73, 1207 (1951). 25 G. L'abb6, J. E. Galle, and A. , 303 (1970). 26 S. Corsano and R. Inverardi, Ric. Sci. 29, 74 (1959); Chem. Abstr. 53, 17108 (1959). 27 L. Birkofer, A. Ritter, and H. Uhlenbrauck, Chem. Ber. 96,3280 (1963). 28 A. Dornow and K. Rombusch, Chem. Ber. 91, 1841 (1958). 29 W. G. Finnegan and W.

Rico, and M. C. Saldana, J. HeterocycZ. Chem. 6, 921 (1969). 39 C. F. S. Patent 3,324,085; Chem. Abstr. 67, 44802 (1967). 40 S. Maffei and G. F. Bettinetti, Ann. Chim. (Rome)47, 1286 (1957);Chem. Abstr. 52, 7292g (1958). 41 H. Gold, Ann 688, 205 (1965). 42 A. Treibs and K. Jacob,Ann 737, 176 (1970). 43H. G. Adolph, J. Org. Chena. 36, 806 (1971). 34 35 R. H H b Sec. 1 1,2,3-TRIAZOLES 39 3. 27,4 4 * 4 5 Typical conditions involve heating the components a t 150”-170” for 6-20 hours. The products are always 2-trimethylsilyltriazoles, indicating that migration of the trimethylsilyl group from N-1 to N-2 ha5 occurred.

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Advances in Heterocyclic Chemistry, Vol. 16 by A. R. Katritzky, A. J. Boulton


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