By Zard S.Z.

ISBN-10: 1559383216

ISBN-13: 9781559383219

This sequence is designed to supply a automobile during which investigators, who've confirmed a excessive measure of competence in a few point of unfastened radical chemistry, can current a selected niche. The sequence incorporates a big variety of issues that are of present curiosity.

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Wiley-Interscience: New York, 1982; pp. 203-232. 5. French, J. C; Bartz, Q. ; Dion, H. W. / Antibiot. (Japan) 1973,26,272-283. 6. Haskell, T. ; Fusari, S. ; Frohardt, R. R; Bartz, Q. R. J. Am. Chem. Soc. 1952, 74,599-602. 7. Gould, S. ; Martinkus, K. -H. / Am. Chem. Soc. 1981, 103, 2871-2872. 8. Gould, S. ; Thiruvengadam, T. K. J. Am. Chem. Soc. 1981,103,6752-6754. 9. ; Gould, S. J. J. Am. Chem. Soc. 1988,7/0,5785-5791. 10. Reming, P E; Knaggs, A. ; Floss, H. G. / Am. Chem. 5oc. 1994,7/(5,4137-4138.

13. Moss, M. ; Frey, P A. J. Biol. Chem. 1987,262,14859-14862. 14. ; Moss, M. ; Frey, P A. J. Biol. Chem. 1989,264,1357-1360. 15. Moss, M. L; Frey, P A. / Biol. Chem. 1990,255,18112-18115. 16. ; Frey, P A. / Am. Chem. Soc. 1990, 7/2, 8982-8983. 17. Ballinger, M. D. Thesis, University of Wisconsin-Madison, 1993. 18. Ballinger, M. ; Reed, G. ; Frey, P A. Biochemistry 1992,31,949-953. 19. Ballinger,M. ; Reed, G. H. Biochemistry 1992,31,10782-10789. 20. Ballinger, M. ; Reed, G. ; LoBrutto, R. 34, 10086-10093.

3-(l-Pyrrolidinyl)propenoate (8), in contrast, requires no precautions for handling and may be considered as a synthetic equivalent of formylacetate. ^ The reactions of various electron-rich olefins 4b and 4d-h are summerized in Table 1. As well as P-unsubstituted silyl enol ethers 4b and 4c, p-substituted silyl enol ethers 4d and 4e and ketene silyl acetal 4f reacted with 8 to provide keto esters 9 in good yield. The reaction of 8 with disubstituted olefins 4g and 4h also proceeded reasonably, giving a-methylene lactones in moderate yield.

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Advances in Free Radical Chemistry, Volume 2 by Zard S.Z.

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